Another tricky way to show edges is to make surfaces of all the regions and then use suma to draw the surface nodes in the afni GUI.
mkdir surfs
cd surfs
IsoSurface -isorois+dsets -input ../myrois.nii -o mysurfs.gii
Then start afni in the volumetric data directory and suma with the surfaces you just created.
afni -niml ../
suma -onestate -i *.gii -sv ../myrois.nii
In AFNI, set the underlay to some desired dataset. In suma, press 't' for suma to talk to afni, and the surface edges will appear in the afni viewer. You can control the thickness of the edge lines with the Control Surfaces menu in afni.